Publications

Nature of cyanoargentate bridges defining spin crossover in new 2D Hofmann clathrate analogues
V.Y. Sirenko, O.I. Kucheriv, S. Shova, S.I. Shylin, V. Ksenofontov, I.O. Fritsky, W.Tremel and I.A. Gural'skiy
Dalton Trans., 2024,53, 4251-4259, DOI: 10.1039/D3DT04372J
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Colossal barocaloric effect of the spin-crossover compound {Fe(pz)2(BH3CN)2} near room temperature
R. Li, Z. Zhang, Y.S. Bibik, I.A. Gural'skiy, I.V. Zatovsky, Z. Liu, Q. Li, B. Li, G. Levchenko, B. Liu
Appl. Phys. Lett., 2024, 124, 122202, DOI: 10.1063/5.0195431
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2D hybrid organic-inorganic perovskite displaying narrow-band violet-blue photoluminescence
O.I. Kucheriv, V.Y. Sirenko, S. Shova, I.A. Gural'skiy
J. Lumin., 2024, 275, 120753, DOI: 10.1016/j.jlumin.2024.120753
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Switchable nanoparticles based on Fe(II)-Au(I) spin-crossover coordination polymer
Y. S. Bibik, I.O. Fritsky, O.I. Kucheriv, A.I. Marynin, G. Molnár, L. Salmon, A. Bousseksou, I.A. Gural'skiy
J. Mol. Struct., 2024, 139302, DOI: 10.1016/j.molstruc.2024.139302
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Histidine-based hybrid perovskites as promising materials for wide wavelength photodetection
V.Y. Sirenko, O.I. Kucheriv, S. Shova, I.A. Gural'skiy
Appl. Mater. Today, 2024, 41, 102452, DOI: 10.1016/j.apmt.2024.102452
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Quantum dots assembled from an aziridinium based hybrid perovskite displaying tunable luminescence
O. A. Semenikhin, O. I. Kucheriv, L. Sacarescu, S. Shova, I. A. Gural'skiy
Chem. Commun., 2023, 59, 3566-3569, DOI: 10.1039/D2CC06791A
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Lead-free 3D hybrid perovskites based on an aziridinium cation
O.I. Kucheriv, V.Y. Sirenko, H.R. Petrosova, V.A. Pavlenko, S. Shova and I. A. Gural'skiy
Inorg. Chem. Front., 2023,10, 6953-6963, DOI: 10.1039/D3QI00872J
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Phase Transitions, Dielectric Response, and Nonlinear Optical Properties of Aziridinium Lead Halide Perovskites
M. Mączka, M. Ptak, A. Gągor, J.K. Zaręba, X. Liang, S. Balčiu̅nas, O.A. Semenikhin, O.I. Kucheriv, I.A. Gural’skiy, S. Shova, A. Walsh, J. Banys, and M. Šimėnas
Chem. Mater. 2023, 35, 22, 9725–9738, DOI: 10.1021/acs.chemmater.3c02200
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Structural diversity in proline-based lead bromide chiral perovskites
V. Y. Sirenko, O. I. Kucheriv, I.O. Fritsky, E. Gumienna-Kontecka, I.-A. Dascălu, S. Shova, I. A. Gural'skiy
Dalton Trans., 2023, 52, 10545-10556, DOI: 10.1039/D3DT02056H
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Chiral 2D organic-inorganic hybrid perovskites based upon L-histidine
V. Y. Sirenko, O.I. Kucheriv, E. Gumienna-Kontecka, S. Shova, I. A. Gural'skiy
Dalton Trans., 2022, 51, 16536-16544, DOI: 10.1039/D2DT03025J
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Highly Porous Cyanometallic Spin-Crossover Frameworks Employing Pyridazino[4,5-d]pyridazine Bridge
V. M. Hiiuk, S. Shova, K. V. Domasevitch, Il'ya A. Gural'skiy
Inorganics, 2022, 10, 11, 195, DOI: 10.3390/inorganics10110195
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Aziridinium cation templating 3D lead halide hybrid perovskites
H.R. Petrosova, O.I. Kucheriv, S. Shova, I.A. Gural'skiy
Chem. Commun., 2022, 58, 5745-5748, DOI: 10.1039/D2CC01364A
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Four-Step Spin Crossover in a New Cyano-Bridged Iron-Silver Coordination Polymer
O. I. Kucheriv, S. I. Shylin, V. Y. Sirenko, V. Ksenofontov, W. Tremel, I.-A. Dascălu, S. Shova, I. A. Gural'skiy
Chem. Eur. J., 2022, 28, e202200924 , DOI: 10.1002/chem.202200924
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Solvatomorphism, polymorphism and spin crossover in bis[hydrotris(1,2,3-triazol-1-yl)borate]iron(II)
O. Ye. Horniichuk, K. Ridier, G. Molnár, V. O. Kotsyubynsky, S. Shova, V. M. Amirkhanov,
I. A. Gural'skiy, L. Salmon, A. Bousseksou
New J. Chem., 2022, 46, 11734-11740, DOI: 10.1039/D2NJ01471H
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A Vanadium Dioxide-PMMA Composite For Microwave Radiation Switching
O. I. Kucheriv, V. I. Grygoruk, V. V. Oliynyk, V. V. Zagorodnii, V. L. Launets, A. Rotaru,
I. A. Gural'skiy
ChemPlusChem, 2022, 87, e202200107, DOI: 10.1002/cplu.202200107
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Hybrid organic-inorganic perovskites as microwave radiation switches
O. I. Kucheriv, V. V. Oliynyk, V. V. Zagorodnii, V. L. Launetz, I. O. Fritsky, I. A. Gural'skiy
Mater. Adv., 2022, 3, 8260-8266, DOI: 10.1039/D2MA00633B
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Cooperative Spin Crossover above Room Temperature in the Iron(II) Cyanoborohydride-Pyrazine Complex
Y. S. Bibik, S. Shova, A. Rotaru, S. I. Shylin, I. O. Fritsky, R. D. Lampeka, I. A. Gural'skiy
Inorg. Chem. 2022, 61, 14761–14769, DOI: 10.1021/acs.inorgchem.2c02177
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Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)
V. M. Hiiuk, S. I. Shylin, D. D. Barakhtii, D. M. Korytko, V. O. Kotsyubynsky, A. Rotaru, S. Shova, I. A. Gural'skiy
Inorg. Chem. 2022, 61, 4, 2093–2104, DOI: 10.1021/acs.inorgchem.1c03302
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1D iron(ii)-1,2,4-triazolic chains with spin crossover assembled from discrete trinuclear complexes
S. I. Shylin, S. Shova, H. J. Shepherd, V. Ksenofontov, W. Tremel, I.A. Gural'skiy
Dalton Trans., 2022, 51, 2364-2369, DOI: 10.1039/D2DT00004K
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Tunable mechanical properties of [Fe(pyrazine){Au(CN)2}2]
Y. S.Bibik, J. E. Angulo-Cervera, R. D. Lampeka, I. A.Gural'skiy
Polymer, 2022, 238, 124410, DOI: 10.1016/j.polymer.2021.124410
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Spin crossover in iron(II) Hofmann clathrates analogues with 1,2,3-triazole
I.S. Kuzevanova, O.I. Kucheriv, V.M. Hiiuk, D.D. Naumova, S. Shova, S.I. Shylin, V.O. Kotsyubynsky, A. Rotaru, I.O. Fritsky, I.A. Gural'skiy
Dalton Trans., 2021, 50, 9250-9258, DOI: 10.1039/D1DT01544C
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Chiral Organic-Inorganic Lead Halide Perovskites Based on α-Alanine
V.Y. Sirenko, O.I. Kucheriv, D.D. Naumova, I.Fesich, R. Linnik, A. Dascalu, S. Shova, I.O. Fritsky, I.A. Gural'skiy
New J. Chem., 2021, 45, 12606-12612, DOI: 10.1039/D1NJ01089A
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Pressure gradient effect on spin-crossover materials: Experiment vs theory
I. Rusu, I. C. Manolache-Rusu, A. Diaconu, O. Palamarciuc, I. A. Gural'skiy, G. Molnar, A. Rotaru
J. Appl. Phys., 2021, 129, 064501, DOI: 10.1063/5.0042582
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Spin Crossover in FeII Cyanometallic Frameworks
O.I. Kucheriv, I.O. Fritsky and Il'ya A. Gural'skiy
Inorg. Chim. Acta, 2021, 521, 120303, DOI: 10.1016/i.ica.2021.120303
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Influence of the Ultra-Slow Nucleation and Growth Dynamics on the Room-Temperature Hysteresis of Spin-Crossover Single Crystals
V.M. Hiiuk, K. Ridier, I.A. Gural'skiy, A.A. Golub, I.O. Fritsky, G. Molnar, W. Nicolazzi and A. Bousseksou
Chem. Phys. Lett, 2021, 770, 138442, DOI: 10.1016/j.cplett.2021.138442
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Direct Synthesis of Spin-Crossover Complexes: An Unexpectedly Revealed New Iron-Triazolic Structure
V.Y. Sirenko, O.I. Kucheriv, A. Rotaru, I.O. Fritsky and Il'ya A. Gural'skiy
Eur. J. Inorg. Chem., 2020, 2020, 48, 4523-4531, DOI: 10.1002/ejic.202000848
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Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)2}2]
A.-C. Gheorghe, Y.S. Bibik, O.I. Kucheriv, D.D. Barakhtii, M.-V. Boicu, I. Rusu, A. Diaconu, I.A. Gural'skiy, G. Molnar and A. Rotaru
Magnetochemistry 2020, 6, 3, 31, DOI: 10.3390/magnetochemistry6030031
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New Applications of Spin-Crossover Complexes: Microwave Absorption, Chirooptical Switching and Enantioselective Detection
Kucheriv O.I., Oliynyk V.V., Zagorodnii V.V., Launets V.L., Fritsky I.O. and Gural'skiy I.A.
In Modern Magnetic and Spintronic Materials. NATO Science for Peace and Security Series B: Physics and Biophysics, 2020, 6, 119-143, DOI: 10.1007/978-94-024-2034-0_6
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Interaction of Microwave Radiation with Nanostructured Composites: Toward Effective Selective Adsorbers
V.I.Grygoruk, V.V. Oliynyk, V.V. Zagorodnii, L.Yu. Matzui, L.L. Vovchenko, I.A. Gural'skiy, O.I. Kucheriv, M.O. Popov, V.L. Launets, A.L. Nikytenko and S.Vitusevich
In Interaction of physical fields with nanostructured materials, 2020, 5, 195-250.
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Tunable microwave absorption of switchable complexes operating near room temperature
O.I. Kucheriv, V.V. Oliynyk, V.V. Zagorodnii, V.L. Launets, O.V. Penkivska, I.O. Fritsky and I.A. Gural'skiy
RSC Adv., 2020, 10, 21621-21628, DOI: 10.1039/D0RA02236E
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Hofmann-Like Frameworks Fe(2-methylpyrazine)n[M(CN)2]2 (M = Au, Ag): Spin-Crossover Defined by the Precious Metal
S.I. Shylin, O.I. Kucheriv, S. Shova, V. Ksenofontov, W. Tremel and I.A. Gural'skiy
Inorg. Chem., 2020, 59, 9, 6541-6549, DOI: 10.1021/acs.inorgchem.0c00627
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Spin crossover in 2D iron(II) phthalazine cyanometallic complexes
V.M. Hiiuk, S. Shova, A. Rotaru, A.A. Golub, I.O. Fritsky and I.A. Gural'skiy
Dalton Trans., 2020, 49, 5302-5311, DOI: 10.1039/D0DT00783H
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Pyridazine-Supported Polymeric Cyanometallates with Spin Transitions
I. A. Gural'skiy, S. I. Shylin, V. Ksenofontov, W. Tremel
Eur. J. Inorg. Chem. 2019, 2019, 4532-4537, DOI: 10.1002/ejic.201900782
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Room temperature hysteretic spin crossover in a new cyanoheterometallic framework
V. M. Hiiuk, S. Shova, A. Rotaru, V. Ksenofontov, I. O. Fritsky and I. A. Gural'skiy
Chem. Commun., 2019, 55, 3359–3362, DOI: 10.1039/C8CC10260K
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Multiple spin phases in a switchable Fe(II) complex: polymorphism and symmetry breaking effects
H. Hang, B. Fei, X. Q. Chen, M. L. Tong, V. Ksenofontov, I. A. Gural'skiy, X. Bao
J. Mater. Chem. C 2018, 6, 3352-3361, DOI: 10.1039/C7TC05111E
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Spin-State Dependent Redox Catalytic Activity of a Switchable Iron(II) Complex
I.A. Gural'skiy, S.I. Shylin, V. Ksenofontov, W. Tremel
Eur. J. Inorg. Chem. 2017, 2017, 3125-3131, DOI: 10.1002/ejic.201700454
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Synthesis, crystal structures and spectral characterization of chiral 4-R-1,2,4-triazoles
Il'ya A. Gural'skiy, Viktor A. Reshetnikov, Irina V. Omelchenko, Agnieszka Szebesczyk, Elzbieta Gumienna-Kontecka, Igor O. Fritsky
Journal of Molecular Structure 2017, 1127, 164-168, DOI: 10.1016/j.molstruc.2016.07.094
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Co-Co and Co-Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects
B. Fei, J. Zhou, Z. Yan, S. I. Shylin, V. Ksenofontov, I. A. Gural'skiy and X. Bao
CrystEngComm, 2017, 19, 7079–7082, DOI: 10.1039/C7CE01826F
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Spin-Crossover Materials towards Microwave Radiation Switches
O. I. Kucheriv, V. V. Oliynyk, V. V. Zagorodnii, V. L. Launets, I. A. Gural'skiy
Scientific Reports, 2016, 6, 38334 DOI:10.1038/srep38334
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Cooperative High-Temperature Spin Crossover Accompanied by a Highly Anisotropic Structural Distortion
I. A. Gural'skiy, B. O. Golub, S. I. Shylin, V. Ksenofontov, H. J. Shepherd, P. R. Raithby, W. Tremel and I. O. Fritsky
Eur. J. Inorg. Chem., 2016, 2016, 3191-3195, DOI: 10.1002/ejic.201600406
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High temperature spin crossover in [Fe(pyrazine){Ag(CN)2}2] and its solvate
I. A. Gural'skiy, S. I. Shylin, B. O. Golub, V. Ksenofontov, I. O. Fritsky and W. Tremel
New J. Chem., 2016, 40, 9012–9016, DOI: 10.1039/C6NJ01472K
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Spin Crossover in Fe(II)-M(II) Cyanoheterobimetallic Frameworks (M = Ni, Pd, Pt) with 2-Substituted Pyrazines
O. I. Kucheriv, S. I. Shylin, V. Ksenofontov, S. Dechert, M. Haukka, I. O. Fritsky and I. A. Gural'skiy
Inorg. Chem., 2016, 55, 4906-4914, DOI: 10.1021/acs.inorgchem.6b00446
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Enantioselective Guest Effect on the Spin State of a Chiral Coordination Framework
I. A. Gural'skiy, O. I. Kucheriv, S. I. Shylin, V. Ksenofontov, R. A. Polunin and I. O. Fritsky
Chem. Eur. J., 2015, 21, 18076-18079, DOI: 10.1002/chem.201503365
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Chiral spin crossover nanoparticles and gels with switchable circular dichroism
I. A. Gural'skiy, V. A. Reshetnikov, A. Szebesczyk, E. Gumienna-Kontecka, A. I. Marynin, S. I. Shylin, V. Ksenofontov, I. O. Fritsky
J. Mater. Chem. C 2015, 3, 4737–4741, DOI: 10.1039/C5TC00161G
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Iron (II) isothiocyanate complexes with substituted pyrazines: Experimental and theoretical views on their electronic structure
S. I. Shylin, I. A. Gural'skiy, D. Bykov, S. Demeshko, S. Dechert, F. Meyer, M. Hauka, I. O. Fritsky
Polyhedron 2015, 87, 147–155, DOI: 10.1016/j.poly.2014.11.016
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