Publications

Small Cations for Engineering 3D Hybrid Perovskites
O.I. Kucheriv, V.Y. Sirenko, I.A. Gural'skiy
Chem. Eur. J., 2025, 31, 40, e202500765, DOI: 10.1002/chem.202500765
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Aziridinium cation as a versatile template for hybrid organic–inorganic perovskites of all dimensionalities
O.I. Kucheriv, O.A. Semenikhin, Y.S. Bibik, I. Bardyk, S. Shova and I.A. Gural'skiy
Inorg. Chem. Front., 2025,12, 7375-7391, DOI: 10.1039/D5QI01090J
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FAIR data: CCDC CIFs

Aziridinium 3D Perovskites: Toward Semiconducting Films with Tunable Band Gaps
O.I. Kucheriv, H.R. Petrosova, V.Y. Sirenko, O.A. Semenikhin, M. Choghaei, K. Meerholz, S. Olthof, I.A. Gural’skiy
Chem. Mater. 2025, 37, 13, 4758–4767, DOI: 10.1021/acs.chemmater.5c00671
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B-Site Mixing Effects in Hybrid Perovskites: Phase Transitions and Dielectric Response of MAPb1–xSnxBr3
G. Rimkus,Se Balciunas, H.R. Petrosova, O.I. Kucheriv, R. Lemežis, V. Klimavičius, V. Kalendra, J. Banys, I.A. Gural’skiy, M. Šimėnas
Chem. Mater. 2025, 37, 3, 1314–1320, DOI: 10.1021/acs.chemmater.4c03381
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Fine-tuning of optical band gap in mixed halide aziridinium lead perovskites
O.I. Kucheriv, D.A. Haleliuk, S. Shova and I.A. Gural'skiy
Dalton Trans., 2025,54, 1618-1624, DOI: 10.1039/D4DT02879A
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FAIR data: CCDC CIFs

Nature of cyanoargentate bridges defining spin crossover in new 2D Hofmann clathrate analogues
V.Y. Sirenko, O.I. Kucheriv, S. Shova, S.I. Shylin, V. Ksenofontov, I.O. Fritsky, W.Tremel and I.A. Gural'skiy
Dalton Trans., 2024,53, 4251-4259, DOI: 10.1039/D3DT04372J
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Colossal barocaloric effect of the spin-crossover compound {Fe(pz)2(BH3CN)2} near room temperature
R. Li, Z. Zhang, Y.S. Bibik, I.A. Gural'skiy, I.V. Zatovsky, Z. Liu, Q. Li, B. Li, G. Levchenko, B. Liu
Appl. Phys. Lett., 2024, 124, 122202, DOI: 10.1063/5.0195431
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2D hybrid organic-inorganic perovskite displaying narrow-band violet-blue photoluminescence
O.I. Kucheriv, V.Y. Sirenko, S. Shova, I.A. Gural'skiy
J. Lumin., 2024, 275, 120753, DOI: 10.1016/j.jlumin.2024.120753
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Switchable nanoparticles based on Fe(II)-Au(I) spin-crossover coordination polymer
Y. S. Bibik, I.O. Fritsky, O.I. Kucheriv, A.I. Marynin, G. Molnár, L. Salmon, A. Bousseksou, I.A. Gural'skiy
J. Mol. Struct., 2024, 139302, DOI: 10.1016/j.molstruc.2024.139302
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Histidine-based hybrid perovskites as promising materials for wide wavelength photodetection
V.Y. Sirenko, O.I. Kucheriv, S. Shova, I.A. Gural'skiy
Appl. Mater. Today, 2024, 41, 102452, DOI: 10.1016/j.apmt.2024.102452
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Quantum dots assembled from an aziridinium based hybrid perovskite displaying tunable luminescence
O. A. Semenikhin, O. I. Kucheriv, L. Sacarescu, S. Shova, I. A. Gural'skiy
Chem. Commun., 2023, 59, 3566-3569, DOI: 10.1039/D2CC06791A
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Lead-free 3D hybrid perovskites based on an aziridinium cation
O.I. Kucheriv, V.Y. Sirenko, H.R. Petrosova, V.A. Pavlenko, S. Shova and I. A. Gural'skiy
Inorg. Chem. Front., 2023,10, 6953-6963, DOI: 10.1039/D3QI00872J
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Phase Transitions, Dielectric Response, and Nonlinear Optical Properties of Aziridinium Lead Halide Perovskites
M. Mączka, M. Ptak, A. Gągor, J.K. Zaręba, X. Liang, S. Balčiu̅nas, O.A. Semenikhin, O.I. Kucheriv, I.A. Gural’skiy, S. Shova, A. Walsh, J. Banys, and M. Šimėnas
Chem. Mater. 2023, 35, 22, 9725–9738, DOI: 10.1021/acs.chemmater.3c02200
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Structural diversity in proline-based lead bromide chiral perovskites
V. Y. Sirenko, O. I. Kucheriv, I.O. Fritsky, E. Gumienna-Kontecka, I.-A. Dascălu, S. Shova, I. A. Gural'skiy
Dalton Trans., 2023, 52, 10545-10556, DOI: 10.1039/D3DT02056H
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Chiral 2D organic-inorganic hybrid perovskites based upon L-histidine
V. Y. Sirenko, O.I. Kucheriv, E. Gumienna-Kontecka, S. Shova, I. A. Gural'skiy
Dalton Trans., 2022, 51, 16536-16544, DOI: 10.1039/D2DT03025J
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Highly Porous Cyanometallic Spin-Crossover Frameworks Employing Pyridazino[4,5-d]pyridazine Bridge
V. M. Hiiuk, S. Shova, K. V. Domasevitch, Il'ya A. Gural'skiy
Inorganics, 2022, 10, 11, 195, DOI: 10.3390/inorganics10110195
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Aziridinium cation templating 3D lead halide hybrid perovskites
H.R. Petrosova, O.I. Kucheriv, S. Shova, I.A. Gural'skiy
Chem. Commun., 2022, 58, 5745-5748, DOI: 10.1039/D2CC01364A
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Four-Step Spin Crossover in a New Cyano-Bridged Iron-Silver Coordination Polymer
O. I. Kucheriv, S. I. Shylin, V. Y. Sirenko, V. Ksenofontov, W. Tremel, I.-A. Dascălu, S. Shova, I. A. Gural'skiy
Chem. Eur. J., 2022, 28, e202200924 , DOI: 10.1002/chem.202200924
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Solvatomorphism, polymorphism and spin crossover in bis[hydrotris(1,2,3-triazol-1-yl)borate]iron(II)
O. Ye. Horniichuk, K. Ridier, G. Molnár, V. O. Kotsyubynsky, S. Shova, V. M. Amirkhanov,
I. A. Gural'skiy, L. Salmon, A. Bousseksou
New J. Chem., 2022, 46, 11734-11740, DOI: 10.1039/D2NJ01471H
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A Vanadium Dioxide-PMMA Composite For Microwave Radiation Switching
O. I. Kucheriv, V. I. Grygoruk, V. V. Oliynyk, V. V. Zagorodnii, V. L. Launets, A. Rotaru,
I. A. Gural'skiy
ChemPlusChem, 2022, 87, e202200107, DOI: 10.1002/cplu.202200107
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Hybrid organic-inorganic perovskites as microwave radiation switches
O. I. Kucheriv, V. V. Oliynyk, V. V. Zagorodnii, V. L. Launetz, I. O. Fritsky, I. A. Gural'skiy
Mater. Adv., 2022, 3, 8260-8266, DOI: 10.1039/D2MA00633B
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Cooperative Spin Crossover above Room Temperature in the Iron(II) Cyanoborohydride-Pyrazine Complex
Y. S. Bibik, S. Shova, A. Rotaru, S. I. Shylin, I. O. Fritsky, R. D. Lampeka, I. A. Gural'skiy
Inorg. Chem. 2022, 61, 14761–14769, DOI: 10.1021/acs.inorgchem.2c02177
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Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)
V. M. Hiiuk, S. I. Shylin, D. D. Barakhtii, D. M. Korytko, V. O. Kotsyubynsky, A. Rotaru, S. Shova, I. A. Gural'skiy
Inorg. Chem. 2022, 61, 4, 2093–2104, DOI: 10.1021/acs.inorgchem.1c03302
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1D iron(ii)-1,2,4-triazolic chains with spin crossover assembled from discrete trinuclear complexes
S. I. Shylin, S. Shova, H. J. Shepherd, V. Ksenofontov, W. Tremel, I.A. Gural'skiy
Dalton Trans., 2022, 51, 2364-2369, DOI: 10.1039/D2DT00004K
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Tunable mechanical properties of [Fe(pyrazine){Au(CN)2}2]
Y. S.Bibik, J. E. Angulo-Cervera, R. D. Lampeka, I. A.Gural'skiy
Polymer, 2022, 238, 124410, DOI: 10.1016/j.polymer.2021.124410
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Spin crossover in iron(II) Hofmann clathrates analogues with 1,2,3-triazole
I.S. Kuzevanova, O.I. Kucheriv, V.M. Hiiuk, D.D. Naumova, S. Shova, S.I. Shylin, V.O. Kotsyubynsky, A. Rotaru, I.O. Fritsky, I.A. Gural'skiy
Dalton Trans., 2021, 50, 9250-9258, DOI: 10.1039/D1DT01544C
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Chiral Organic-Inorganic Lead Halide Perovskites Based on α-Alanine
V.Y. Sirenko, O.I. Kucheriv, D.D. Naumova, I.Fesich, R. Linnik, A. Dascalu, S. Shova, I.O. Fritsky, I.A. Gural'skiy
New J. Chem., 2021, 45, 12606-12612, DOI: 10.1039/D1NJ01089A
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Pressure gradient effect on spin-crossover materials: Experiment vs theory
I. Rusu, I. C. Manolache-Rusu, A. Diaconu, O. Palamarciuc, I. A. Gural'skiy, G. Molnar, A. Rotaru
J. Appl. Phys., 2021, 129, 064501, DOI: 10.1063/5.0042582
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Spin Crossover in FeII Cyanometallic Frameworks
O.I. Kucheriv, I.O. Fritsky and Il'ya A. Gural'skiy
Inorg. Chim. Acta, 2021, 521, 120303, DOI: 10.1016/i.ica.2021.120303
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Influence of the Ultra-Slow Nucleation and Growth Dynamics on the Room-Temperature Hysteresis of Spin-Crossover Single Crystals
V.M. Hiiuk, K. Ridier, I.A. Gural'skiy, A.A. Golub, I.O. Fritsky, G. Molnar, W. Nicolazzi and A. Bousseksou
Chem. Phys. Lett, 2021, 770, 138442, DOI: 10.1016/j.cplett.2021.138442
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